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(i) The carbon in C-Cl bond in chlorobenzene is sp2 hybridised, while in CH3-Cl is sp3 hybridised. In sp2 hybrid orbitals have more of s -character and hence the carbon if chlorobenzene withdraws the electron pair between C-Cl with greater force. As a result, C-Cl bond is shorter than CH3-Cl.

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(b)Hybridisations of C in C−Cl in chlorobenzene and cyclohexyl chloride are sp2 and sp3, respecti

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